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年度	106	專案性質	實驗性質
專案類別	研究專案	研究主題	調查
申請機構	崑山科技大學	申請系所	環工系
專案主持人	高年信	職等/職稱	副教授
專案中文名稱	開發油品污染埸址中土壤與底泥之生物指標化合物之鑑定與量化應用技術
中文關鍵字	油品、土壤、底泥、生物指標化合物
專案英文名稱	Development of identification and quantification technology for the biomarker compounds in the oil polluted soil and sediment.
英文關鍵字	Oil products, Soil, Sediment, Biomarkers
執行金額	800,000元
執行期間	2017/1/9 至 2017/11/30
計畫中文摘要	油品中生物指標化合物具有高度抗風化與污染源有直接連結性之原生物質，環境中含有之生物指標化合物因為年代久遠或因濃度太低導致非常難以鑑定而且大部份生物指標化合物並無商用化標準品使得定量技術更為複雜。本研究目的為開發生物指標化合物類污染物程序與提升鑑定與量化技術之精準度，建置有效之鑑定與量化技術。本年度計畫已經完成實驗系統設計及執行，建置了微量生物指標化合物淨化技術並依據CG4 潤滑油為基礎樣本鑑定出37 種terpne 生物指標化合物及完成定性及定量。期中也依據我們研究團隊的期初研究成果發表了一篇論文(SCI 2.522/2017) ，本期末也完成一篇論文並於投稿程序中。期末依據進度進行河川底泥、溪口底泥、漁港區底泥、加油站土壤、大型儲槽區土壤等取得之現地樣本來進行應用與驗證並擬延續過往之長年研究成果，建立環境法醫程序以鑑定土壤及底泥是否受到油品污染物準確度的技術，並以現地樣本來驗證成果來鑑定出低濃度之油品生物指標化合物，此類主要生物指標化合物類為汽油、柴油、潤滑油等油品含有之adamantanes (金剛烷類C10 到C12) 、BSs (bicyclic sesquiterpanes, 雙環倍半萜類C14 到C16) 、terpanes (萜烷類C18 到C36) 及steranes (甾烷類C28 到C30)等。本研究成果除了可用於未來研擬現有法規所規範之汚染物種以外之政策參考，也可配合整治產業建置污染場址之整治效果評估制度。
計畫英文摘要	Fossil oil products are the anthropengic materials that containing various kinds of weathering resisting biomarker compounds. However, identification technologies are not easy due to the long history or low concentrations of the biomarkers in the environments. Mostly, there are no full scale of commercialized biomarker standards in the market and that makes difficulty in identification process. The objective of the study for the year is to establish an effective and an accurate biomarker identification technology. To date, we have planned, established and conducted a new cleanup process and identified those biomarkers with micro concentrations in the studied based CG4 lubricant sample. Based on our yearly research and the preliminarily study of the project, we had publish a SCI (IF 2.522/2017) paper and another written paper is in the process of submission. To date we have verified the midterm results by the taken environmental samples which includes sediments in the revivers and soils in the contaminated sites. In the final report, we identify those related biomarker compounds in the oil products, which include adamantanes (C10 to C12), BSs (bicyclic sesquiterpanes C14 to C16), terpanes (C18 to C36) and steranes (C28 to C30). In the future, the results of this study can be used as a reference of policy making to develop newer regulations other than the currents. The results can also be used to establish an evaluation system for a treatment efficiency in the contamination site.